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However, Benzophenone-4 is commonly used for other purposes such as extending the shelf lives of products and acting as a color protectant. This ingredient is also known by its other names like 1-phenol-4-sulfonic acid and sulisobenzone. The chemical formula of Benzophenone-4 is C 14 H 12 O 6 S. Who supplies BENZOPHENONE-4 ? Hazardous Substances which may Preclude Goods from the Ecolabel Award as per Article 6(6) of Regulation 66/2010/EC, L 27/1, 30 January 2010, EU. Benzophenones may be found organically in fruits such as grapes . References ^ Merck Index, 11th Edition, 8963. BENZOPHENONE - World Health Organization No p-hydroxybenzohydrol was detected in urine or feces, in a study of pharmacokinetics in rats . [27] Kunz, P. Y., Galicia, H. F., & Fent, K. (2006). Recycled Plastic FCMs per Regulation 10/2011/EU (Union List), Regulation (EU) 2022/1616, OJ L 243 of 20 September 2022, as corrected by a corrigendum, OJ L 244 of 21 September 2022, EU. This substance is used The first contact reaction to benzophenones in sunscreen products was first documented in 1972. and skin care products. Glucam E-20 Humectant gently moisturizes skin, leaving a pleasant afterfeel. This section is based on three sources for information (harmonised classification and labelling (CLH), REACH registrations and CLP notifications). A new Data Availability System is being developed by ECHA. It is based on the relevant subset of substances with harmonised classification listed in Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and The specially coated zinc oxide is designed to offer highest levels of broad-spectrum protection, transparency and dispersibility. Contact dermatitis 56.3 (2007): 153-156. [15], The evidence linking benzophenone and different derivatives to endocrine disruption is complex, and research suggests that different benzophenones have different endocrine effects. Details of substance evaluation by member state competent authorities. ECHA maintains the C&L Inventory, but does not review or verify the accuracy of the information. Octabenzone This list is compiled on the basis of Article 6(5) of Regulation 305/2011/EC on Marketing of Construction Products. Benzophenone. . IUPAC name. Benzophenone. Other names. Diphenylmethanone; phenyl ketone; diphenyl ketone; benzoylbenzene. Identifiers. CAS number. 119-61-9. It is stabilized by PEG-free emulsifier which offers inherent water resistance. WebBenzophenone. Available online: https://oehha.ca.gov/proposition-65/crnr/chemicals-listed-known-state-cause-cancer-or-reproductive-toxicity. Such notifications are required for hazardous substances, as such or in mixtures, as well as for all substances subject to registration, regardless of their hazard. Toxicological Sciences, 90(2), 349-361. However, in some of the hotspots (for example, San Diego County) concentrations may be high enough to raise concerns. Get in touch. WebBenzophenone-4. Substance Information - ECHA We wont share your information and you may opt out at any time. However, these findings are not based on human studies and cannot be a reliable indicator of what happens in people. If used above the prescribed percentage, Benzophenone-4 can also be toxic and bioaccumulative, linking it to cancer. The benzophenones are a group of aromatic ketones that have both pharmaceutical and industrial applications. Other names: Methanone, diphenyl-; -Oxodiphenylmethane; -Oxoditane; Benzene, benzoyl-; Benzoylbenzene; Diphenyl ketone; Diphenylmethanone; Phenyl ketone; Ketone, diphenyl; alpha-Oxodiphenylmethane; alpha-Oxoditane; Adjutan 6016; Kayacure BP; Diphenyl-methanon; NSC 8077; 1-Benzophenone; Cinnarizine M (benzophenone); Type 4 Chloro 4 Hydroxy Benzophenone. The strogen receptor-related receptor 1 (ERR1) and the aryl hydrocarbon receptor (AhR) in adult ovariectomized rats. Spectra-Sorb UV 284 If you have any concerns with your skin or its treatment, see a dermatologist for advice. These are general guidelines. Chemical Structure Description A chemical structure of a molecule includes the arrangement of atoms and the chemical bonds that hold the atoms together. [25] BP2, BP8 and THB stimulate the proliferation (growth and multiplication) of MCF-7 cells, which are used to test for estrogenic activity. Details. As a consequence, REACH registration data will likewise not be updated in Infocards, Brief Profiles, the Advanced search, or the Nanomaterials on the EU market portal. approved by the European Union, this substance Accessed April 18, 2022. Employers are obligated to prevent the exposure of these workers to any agents that may have adverse health effects on either mother or child. DIETHYLAMINO HYDROXYBENZOYL HEXYL BENZOATE, BISETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE, 5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid. air care products, UVINUL EASY UVINUL N 539 T UVINUL P25 UVINUL DS 49 UVINUL BMBM WebHowever, Benzophenone-4 is commonly used for other purposes such as extending the shelf lives of products and acting as a color protectant. These chemicals are not listed under You can help Wikipedia by expanding it. Benzodiazepines (also called benzos) are a class of agents that work in the central nervous system and are used for a variety of medical conditions. Carcinogens, Mutagens and Reproductive substances Not Allowed for Use in Components of Active and Intelligent Materials and Articles (Article 5(2)(c)(i)), Regulation 450/2009/EC, 30 May 2009, EU. [5], It can contaminate drinking water and migrate from food packaging into food. :) You are almost done: please check your mailbox to confirm your email! Benzophenone-4 | Allergic Contact Dermatitis Database WebBenzophenone IUPAC name: Benzophenone Other names Diphenylmethanone; phenyl ketone; diphenyl ketone; benzoylbenzene Identifiers CAS number: 119-61-9: SMILES: O=C(C2=CC=CC=C2)C1=CC=CC=C1: InChI: InChI=1/C13H10O/c14-13(11-7-3-1-4-8-11) 12-9-5-2-6-10-12/h1-10H Properties Molecular formula: C 13 H 10 O Molar mass: 182.217 as processing aid. 4, pp e60567, 2013. It covers their hazardous properties, classification and labelling, and information on how to use them safely. Hazardous Substances for Purposes of Directive 89/391/EEC, 29 June 1989, amended by Regulation 1137/2008/EC, 21 November 2008 (Table 3/Annex VI, CLP; Annex III, 2000/54/EC), EU. (lt), Benzofenona Compatiblity with other products. Cosmetic Restrictions:VI/22. Since ECHA aims to devote our maximum effort to this new system, we can no longer maintain REACH registration data on the current Dissemination Platform. This list contains the Annex I Plastic Food Contact Materials (FCMs) authorised for use in the European Union under Regulation 10/2011/EU. Compatiblity with other products. This substance can be found in complex articles, with no release intended: It can also be used as an emollient and an ingredient to prevent cosmetic products deterioration from sun exposure. A formulation by Koster Keunen. Benzodiazepines (also called benzos) are a class of agents that work in the central nervous system and are used for a variety of medical conditions. Cosmetic Restrictions:VI/22. Benzophenone. Sunscreen Shake Mist SPF46 Pa+++, TRESemm Keratin Smooth Heat Protect Spray, needs Sabonete Gel Limpeza Diria - Pele Normal A Seca, Pears Pure And Gentle Hand Wash With Natural Oils, Pond's Acne Clear Pore Conditioning Toner, Precious skin Thailand Precious Skin Vitamin C Lemon Facial Whitening Serum, 12 Benefits Instant Healthy Hair Treatmeant/Leave-in. Dioxybenzone: Uses, Interactions, Mechanism of Action InfoCards are generated automatically based on the data available at the time of generation. Available online:https://www.cosmeticsinfo.org/ingredients/benzophenone-1/. This list contains a non-exhaustive inventory of substances based on the list of hazardous substances with harmonised classification and labelling (i.e. They act on specific receptors in the brain, called gamma-aminobutyric acid-A (GABA-A) receptors. WebHowever, Benzophenone-4 is commonly used for other purposes such as extending the shelf lives of products and acting as a color protectant. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. It achieves protectionbeyond broad spectrum with a critical wavelength of 377.8 nm. [31] European Food Safety Authority. Benzophenone-4 is an ingredient found in bath, makeup, hair, sunscreens, Benzophenone radical anion Rates of allergic sensitization and irritation to oxybenzone-containing sunscreen products: a quantitative meta-analysis of 64 exaggerated use studies. Benzophenone-4 DermNet provides Google Translate, a free machine translation service. Benzophenone-4 225, no. Product Information. The classifications of the substances listed in the list are based on their harmonised classifications per Table 3 of Annex VI to the CLP Regulation 1272/2008/EC. the electronic edition of the Official Journal of the European Union should be consulted. Benzophenone-4 (Explained + Products) - INCIDecoder For a detailed overview on identified uses and environmental releases, please consult the registered substance factsheet. While the harmonised list covers many hazardous substances, others not listed may also meet the classification criteria in accordance with the CLP Regulation. Generic Name Dioxybenzone DrugBank Accession Number DB11221 Background. Octabenzone - NIST Chemistry WebBook [3] Cosmetics Info. This drug can cause skin and eye irritation . (fi), benzfenonas It helps prevent the integrity of other cosmetic ingredients from deteriorating under the sun. Aquatic Toxicology, vol. by consumers, formula: Note that this may not provide an exact translation in all languages, Home Application Pharmaceutical Industry. Benzophenone. Benzophenone-4 (UV Filter): Cosmetic Ingredient INCI It helps prevent the integrity of Accessed April 18, 2022. 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Importance of prey and predator feeding behaviors for trophic transfer and secondary poisoning. an effective lightweight conditioner. Benzophenones are used as photoinitiators, fragrance enhancers, ultraviolet curing agents, and, occasionally, as flavor ingredients; they are also used in the manufacture of insecticides, agricultural chemicals, and pharmaceuticals and as an additive for plastics, coatings, and adhesives . Grade Medicine Grade. Does not penetrate the skin to a large degree, but enhances the ability of other chemicals to penetrate. It is derived from: Table 3 of Annex VI to CLP, REACH Candidate List of SVHCs, and Directive 2000/54/EC's Annex III (Biological Agents list). This drug's main metabolite is excreted in urine conjugated with glucuronic acid. It spreads well, covers evenly and has built-in water resistance, enhanced using two emollients with excellent barrier characteristics. cosmetics and personal care products. See Sunscreen Article. Kostol STMC #823 is a high performing emulsifier, hair and skin conditioner, and foam booster, making it the perfect choice for conditioning shampoos, and all other hair care applications, especially where a sulfate-free claim is needed. 4, pp e60567, 2013. WebBenzophenone-4. This list contains a non-exhaustive inventory of substances that fall within the scope of the European Union's definition of hazardous chemical and biological substances, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; and (2) Annex III of Directive 2000/54/EC (Biological Agents). Other Names. finger paints and The Waste Framework Directive aims to protect the environment and human health from the generation and management of waste and to improve efficient use of resources. Trade Name: Benzophenone-4: Generic: Sulisobenzone: Sulisobenzone Other Names: Benzophenone-4, Sulfisobenzone, Sulisobenzone: Type: Formula: C 14 H 12 O 6 S: Weight: Average: 308.3 Monoisotopic: 308.03545928 : Groups: Experimental: Therapeutic Class: Manufacturer: Available Country: Last Updated: June 7, 2022 at 8:58 pm 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid 7, pp 369-79, 2011. Dermatology Made Easybook. [2] [3] Its sodium salt, sulisobenzone sodium, is also referred to as benzophenone-5 . Use descriptors are adapted from ECHA guidance to improve readability and may not correspond textually to descriptor codes described in Chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment. Topical sunscreens and other cosmetics are the sources of these allergens in the majority of patients, however reports of reactions secondary to use of industrial products also exist. It provides broadband UV absorption (UVA II and UVB). WebBenzophenone, benzophenone-2, benzophenone-3, benzophenone-4, and benzophenone-5 restricted in cosmetics in United States and oxybenzone is restricted in Octabenzone Hazardous Substances per Article 2(11) of End-of-Life Vehicles Directive 2000/53/EC, 21 October 2000, amended by Directive 2020/363/EU, 5 March 2020 (based on Table 3/Annex VI of CLP), EU. List of 146 substance with endocrine disruption classifications prepared in the expert meeting. If the substance is covered by more than one CLH entry (e.g. This ingredient is also known by Hazardous Substances - Article 2(b)(i), Directive 98/24/EC on Protection of Workers from Chemical Agent-related Risks, 5 May 1998 (Table 3 of Annex VI to CLP, as amended), EU. Sun Care: Water-in-Oil (W/O) Broad Spectrum Protection Daily Facial Moisturizer by DuPont Tate and Lyle. Accessed April 18, 2022. indoor use in long-life materials with low release rate (e.g. 204-337-6, CAS no. WebOther names: Methanone, [2-hydroxy-4- (octyloxy)phenyl]phenyl-; Benzophenone, 2-hydroxy-4- (octyloxy)-; Benzon OO; Benzophenone-12; Cyasorb UV 531; Spectra-Sorb UV 531; UF 4; UV 531; 2-Benzoyl-5- (octyloxy)phenol; 2-Hydroxy-4- (n-octoxy)benzophenone; 2-Hydroxy-4- (n-octyloxy)benzophenone; 2-Hydroxy-4- (octoxy)benzophenone; 2 [17] Studies in adult rats show that benzophenones that are metabolized can exhibit estrogenic activities. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners) and (ATP18) [2] Kim S. & Choi K., Occurrences, toxicities, and ecological risks of benzophenone-3, a common component of organic sunscreen products: A mini-review. Additionally, the classification provided by companies to ECHA in REACH registrations identifies that this substance 5-Benzoyl-4-hydroxy-2-methoxybenzenesulfonic acid Alcohol may potentiate these effects. The list of the other names (synonyms) of Benzophenone (2,4-dinitrophenyl)hydrazone including the registry numbers is given below, if available: Safety Data Sheets Download. The list is derived from a subset of substances on Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). This website uses cookies to ensure you get the best experience on our websites. Hazardous Substances for Purposes of Art. Register for freeForgot Password ? vehicles, Carcinogenesis studies of benzophenone in rats and mice. In these cases, Infocards may not identify all substances in the group.Therefore it does not represent official and legallybinding information. This list contains a non-exhaustive inventory of substances that fall within the European Union's hazardous substance definitions, as provided on: (1) Table 3 of Annex VI to the CLP Regulation 1272/2008/EC; (2) Annex III of Directive 2000/54/EC (Biological Agents); Candidate List of SVHCs; and REACH Annexes XIV and XVII (Authorisation and Restriction lists). the products in which the substance may be used) may refer to uses as intermediate and under controlled conditions, for which there is no consumer exposure. This substance is used for the manufacture of: in processing aids at industrial sites and The listed substances meet the European Union's definitions as hazardous, as provided on: (1) Table 3 of Annex VI to the CLP Regulation (1272/2008/EC); (2) Annex III of Directive 2000/54/EC (Biological Agents); Candidate List of SVHCs; and REACH Annex XIV (Authorisation List). Sulisobenzone 3, pp 255-66, 2007. Available online: http://ec.europa.eu/consumers/cosmetics/cosing/index.cfm?fuseaction=search.details_v2&id=28809. Benzophenones absorb energy throughout the UV range, although the maximum UV absorbance is between 284 and 287 nm for the 2-hydroxybenzophenones . Use. 2023 Campaign for Safe Cosmetics, a program of, Menstrual Care Products and Toxic Chemicals, Ethanolamine Compounds (MEA, DEA, TEA And Others), https://www.cosmeticsinfo.org/ingredients/benzophenone-1/, http://ec.europa.eu/consumers/cosmetics/cosing/index.cfm?fuseaction=search.details_v2&id=28809, http://monographs.iarc.fr/ENG/Monographs/vol101/mono101-007.pdf, https://ntp.niehs.nih.gov/ntp/htdocs/lt_rpts/tr533.pdf, http://www.ewg.org/skindeep/ingredient/700684/BENZOPHENONE/, http://www.ewg.org/skindeep/ingredient/704372/OXYBENZONE/, https://oehha.ca.gov/proposition-65/crnr/chemicals-listed-known-state-cause-cancer-or-reproductive-toxicity, http://ec.europa.eu/environment/archives/docum/pdf/bkh_annex_13.pdf, http://www.efsa.europa.eu/en/efsajournal/pub/1104, Ingredients containing the word benzophenone (for example benzophenone-2). Toxicology and Applied Pharmacology, vol. Hazardous Substances for Purposes of Directive 2008/56/EC (Marine Strategy Framework Directive), 25 June 2008, amended by Directive 2017/845/EU, 18 May 2017, EU. This is unique source of information on the chemicals manufactured and imported in Europe. Also, recent reports of oxybenzone having hormonal effects in animal studies have deterred some people from using sunscreen products. 70, pp 143-57, 2014. Benzophenone-4 [12] Experimental studies suggest benzophenone may lead to several kinds of tumors. The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. Benzophenone. They act on formulation of mixtures. This Water-in-Oil (W/O) Broad Spectrum Protection Daily Facial Moisturizer is a light-feeling formulation which uses Zemea Propanediol to maintain solubility and fluidity of water-soluble sulisobenzone UVB/UVA absorber. disinfectants, pest control products), restriction on "Lead and its compounds"). The list is taken from Annex I to Commission Regulation (EU) No 10/2011. Available online: http://www.efsa.europa.eu/en/efsajournal/pub/1104. Appearance: white flakes or crystals with rose-like odour, Sensitiser: benzophenone and its derivatives, Patch test: 5% or 10% benzophenone in petrolatum, Books about skin diseasesBooks about the skin BRN 2889165. 2,2',4,4'-Tetrahydroxybenzophenone [10][11], Cancer: The California EPAs Proposition 65 list identifies benzophenone as a possible human carcinogen. plastic products, Close polymers, Accessed April 18, 2022. Sunscreening agents are used to prevent sunburn, actinic keratosis, and premature skin aging and to reduce the incidence of skin cancer . [29] European Food Safety Authority. This substance is used in the following products: INCI Names. [20] Other research suggests oxybenzone has estrogenic activity, as indicated by studies of estrogen-sensitive MCF-7 breast cancer cell lines,[21] but other studies found less estrogenic activity. Allergy to benzophenones | DermNet Below are the list of the other names (synonyms) of Benzophenone (2,4-dinitrophenyl)hydrazone including the various registry numbers, if available: disinfectants, pest control products), Therefore, a patch test is recommended before full application. [23] Coronado M., et al. DermNet does not provide an online consultation service.If you have any concerns with your skin or its treatment, see a dermatologist for advice. 4065-45-6. Available online: https://ntp.niehs.nih.gov/ntp/htdocs/lt_rpts/tr533.pdf. coating products, an industrial use resulting in manufacture of another substance (use of intermediates). For additional information about products that might contain Benzophenone-4, visit the Consumer Product Information Database. Available online: http://www.efsa.europa.eu/en/efsajournal/pub/1104. Biopharm Drug Dispos, vol. They can be considered hazardous for purposes of the General Product Safety Directive 2001/95/EC. Danger! You find simplified version here Benzophenone-4, Download Bissoy App to talk Doctor online, Benzophenone-4, Sulfisobenzone, Sulisobenzone. Uvinuc ms 40 If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Toxicology and applied pharmacology, 250(2), 137-146. This substance is used in the following products: This list contains a non-exhaustive inventory of substances based on Art. coating products, We do a Best of INCIDecoder email once a month with the most interesting products and ingredients we bump into. biocides (e.g. in the production of articles, air care products, [2] It is named after the German chemist Wilhelm Michler . Benzophenone pharmaceuticals and UVINUL MS 40 finds application in anti-aging face care products and sunscreens. However, it can be mildly allergic in certain skin types. The factsheets will remain online, but will not be updated. Available online: https://www.cosmeticsinfo.org/ingredients/benzophenone-1/. EWG Skin Deep | What is SULISOBENZONE WebOther names: Methanone, [2-hydroxy-4- (octyloxy)phenyl]phenyl-; Benzophenone, 2-hydroxy-4- (octyloxy)-; Benzon OO; Benzophenone-12; Cyasorb UV 531; Spectra-Sorb CAS Number. This list contains a non-exhaustive inventory of hazardous substances as defined by Article 2(11) of the End-of-Life Vehicles Directive 2000/53/EC. ECHA has no public registered data on the routes by which this substance is most likely to be released to the environment. Language links are at the top of the page across from the title. [1] Brooks AC., et al. Environment International, vol. BENZOPHENONE-4 [38] Kim S. & Choi K., Occurrences, toxicities, and ecological risks of benzophenone-3, a common component of organic sunscreen products: A mini-review. Because they commonly cause contact allergic dermatitis, benzophenones were declared the Contact Allergen of the Year for 2014 by the American Contact Dermatitis Society (ACDS). Hazardous Substances for Purposes of Annex I (3) (Requirements for Construction Works), Regulation 305/2011/EU on Marketing of Construction Products, amended by Regulation 574/2014/EU, 28 May 2014, EU. Get in touch. Benzophenone-1. Release to the environment of this substance can occur from industrial use:

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